Maria Sharapova (RUS x1) - Evgeniya Rodina (RUS)
Qualifier - Madison Brengle (USA)
Qualifier - Olivia Sanchez (FRA)
Martina Muller (GER) - Karin Knapp (ITA x32)
Maria Kirilenko (RUS x21) - Maria Elena Camerin (ITA)
Qualifier - Mara Santangelo (ITA)
Qualifier - Karolina Sprem (CRO)
Kateryna Bondarenko (UKR) - Dinara Safina (RUS x13)
Vera Zvonareva (RUS x11) - Stephanie Foretz (FRA)
Ioana Raluca Olaru (ROM) - Stephanie Cohen-Aloro (FRA)
Qualifier - Akgul Amanmuradova (UZB)
Aleksandra Wozniak (CAN) - Sybille Bammer (AUT x20)
Ai Sugiyama (JPN x31) - Alla Kudryavtseva (RUS)
Olga Govortsova (BLR) - Yuliana Fedak (UKR)
Marta Domachowska (POL) - Rossana De Los Rios (PAR)
Vera Dushevina (RUS) - Elena Dementieva (RUS x7)

Svetlana Kuznetsova (RUS x4) - Aiko Nakamura (JPN)
Vania King (USA) - Violette Huck (FRA)
Alisa Kleybanova (RUS) - Tamarine Tanasugarn (THA)
Aravane Rezai (FRA) - Nadia Petrova (RUS x25)
Francesca Schiavone (ITA x18) - Jill Craybas (USA)
Sanda Mamic (CRO) - Michaella Krajicek (NED)
Sorana-Mihaela Cirstea (ROM) - Anne Kremer (LUX)
Edina Gallovits (ROM) - Victoria Azarenka (BLR x16)
Agnes Szavay (HUN x12) - Ayumi Morita (JPN)
Sabine Lisicki (GER) - Elena Vesnina (RUS)
Petra Kvitova (CZE) - Akiko Morigami (JPN)
Samantha Stosur (AUS) - Shahar Peer (ISR x17)
Anabel Medina Garrigues (ESP x29) - Qualifier
Yung-Jan Chan (TPE) - Tsvetana Pironkova (BUL)
Kaia Kanepi (EST) - Meng Yuan (CHN)
Nuria Llagostera Vives (ESP) - Anna Chakvetadze (RUS x6)

Venus Williams (USA x8) - Tzipora Obziler (ISR)
Stéphanie Dubois (CAN) - Qualifier
Qualifier - Maria-Emilia Salerni (ARG)
Tatiana Perebiynis (UKR) - Flavia Pennetta (ITA x26)
Amelie Mauresmo (FRA x2) - Olga Savchuk (UKR)
Qualifier - Pauline Parmentier (FRA)
Julie Ditty (USA) - Nathalie Dechy (FRA)
Casey Dellacqua (AUS) - Marion Bartoli (FRA x9)
Agnieszka Radwanska (POL x14) - Mariya Koryttseva (UKR)
Séverine Brémond (FRA) - Qualifier
Sara Errani (ITA) - Gisela Dulko (ARG)
Julia Vakulenko (UKR) - Alizé Cornet (FRA x19)
Dominika Cibulkova (SVK x28) - Angelique Kerber (GER)
Milagros Sequera (VEN) - Lilia Osterloh (USA)
Tathiana Garbin (ITA) - Marina Erakovic (NZL)
Qualifier - Jelena Jankovic (SRB x3)

Serena Williams (USA x5) - Ashley Harkleroad (USA)
Mathilde Johansson (FRA) - Camille Pin (FRA)
Ekaterina Makarova (RUS) - Catalina Castano (COL)
Virginia Ruano Pascual (ESP) - Katarina Srebotnik (SLO x27)
Virginie Razzano (FRA x24) - Klara Zakopalova (CZE)
Zi Yan (CHN) - Emilie Loit (FRA)
Tamira Paszek (AUT) - Timea Bacsinszky (SUI)
Ekaterina Bychkova (RUS) - Patty Schnyder (SUI x10)
Nicole Vaidisova (CZE x15) - Qualifier
Anastasia Rodionova (RUS) - Shuai Peng (CHN)
Galina Voskoboeva (RUS) - Youlia Fedossova (FRA)
Petra Cetkocontrea (CZE) - Alona Bondarenko (UKR x23)
Caroline Wozniacki (DEN x30) - Yvonne Meusburger (AUT)
Qualifier - Su-Wei Hsieh (TPE)
Sandra Kloesel (GER) - Lucie Safarova (CZE)
Sofia Arvidsson (SWE) - Ana Ivanovic (SRB x2)