Angelina Jolie is allegedly shown in a "drugs den" in images published by a British tabloid.
Smoking a cigarette the 32-year-old actress looks wide-eyed and rundown, and is seen with a woman smoking heroin in the pictures The Sun newspaper captured from a video.
In the footage, believed to be taken in the 1990s, the 'Tomb Raider' star allegedly reveals her drug use: "I've done coke, heroin, ecstasy, LSD, everything."
But she reportedly adds: "I gave them up long ago."
Jolie also allegedly discusses bizarre sex games, revealing that it is "just a cool thing" to take part in sexual behaviour where people get hurt.
The partner of Brad Pitt, who is currently pregnant with the actor, has previously spoken of her drugs past: "I hate heroin because I've been fascinated with it. I'm not immune, but I won't do it now, at all."
In April, the National Enquirer tabloid reported that a video of Jolie "smoking and snorting heroin" was up for sale at $70 000.