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The leaders, in Japan for a major development conference, urged industrialised nations to make it easier for them to export food, coffee and other products at fair prices.
"Pursuit of unfair trade practices by the big powers as well as difficult access for African products to markets of developed countries continue to penalise our states and significantly destroy their performance in the creation of riches," said Burkina Faso President Blaise Compaore.
Forty heads of states from Africa are participating in the three-day conference to discuss economic growth, stability and climate change.
Japanese Prime Minister Yasuo Fukuda pledged on Wednesday to double aid to Africa by 2012 and to help the continent boost rice production two-fold to ease food shortages.
In recent weeks and months soaring prices for essential foodstuffs such as rice, wheat and corn in some of the world's poorest nations have sparked demonstrations across Africa.
But some African leaders said their countries were more concerned about unfair trade deals than a lack of things to eat.
"There is a big problem of food in the world now and a problem of energy. In Uganda, there is a problem of a different kind. We have too much food and no market to export it to," said Ugandan President Yoweri Museveni.
"Why? Because of bad policies in Europe, America and even in Japan," he added.
He said his country was facing "a real struggle" to get a fair deal for its natural resources, including agricultural and mineral products.
For example, a kilo of unprocessed Ugandan coffee would be sold for one dollar at home but for 14 dollars in Britain after it has been refined, he said.
"I see some people here who are called donors," Museveni told the conference audience.
"I don't know who's helping who"
"Now, I really have a problem with that definition. Because I don't know who's helping who," he added.Fair trade campaigners say that while poor countries have been forced to open up their markets, rich nations have kept unfair practices such as farm subsidies, while multinational companies fail to give farmers a fair deal.
Gabon's President Omar Bongo Ondimba urged Japan to boost direct investment in Africa and open up Japanese markets to African products.
"Japan can weave with Africa a strategic partnership which is mutually beneficial," he said.
The gathering in Yokohama, near Tokyo, is seen as an effort by Japan to expand its influence in Africa, where China and India are also seeking closer ties and supplies of natural resources to fuel their rapid economic growth.
Japan also announced a $2.5-billion initiative to help its companies do business in Africa, paving the way for private sector investment which some African leaders said was sorely lacking.
Tanzanian President Jakaya Kikwete noted that only about two percent of Japanese imports were from Africa.
"Mr. Prime Minister (Fukuda), this must change. What remains to be seen is increased trade and investment, and more development of the Japanese private sector on the African continent," he said.
AFP